14c dating method

For example, it was once standard practice to simply burn whole bones, but the results were eventually seen to be unreliable.

Chemical methods for separating the organic (collagen) from the inorganic (apatite) components of bone created the opportunity to date both components and compare the results.

The diminishing levels via decay means that the effective limit for using c14 to estimate time is about 50,000 years. Subsequent work has shown that the half-life of radiocarbon is actually 5730 ± 40 years, a difference of 3% compared to the Libby half-life.

However, to avoid confusion all radiocarbon laboratories continue to use the half-life calculated by Libby, sometimes rounding it to 5570 years.

The collagen fraction usually yields more reliable dates than the apatite fraction (see Dates on bones).

In addition to various pre-treatments, the sample must be burned and converted to a form suitable for the counter.

This discovery meant that there are three naturally occurring isotopes of carbon: Whereas carbon-12 and carbon-13 are stable isotopes, carbon-14 is unstable or radioactive.

Since there are practical limits to the age range of the method, most samples must be younger than 50,000 years and older than 100 years.

The ensuing atomic interactions create a steady supply of c14 that rapidly diffuses throughout the atmosphere.

Plants take up c14 along with other carbon isotopes during photosynthesis in the proportions that occur in the atmosphere; animals acquire c14 by eating the plants (or other animals).

These so-called "solid-carbon" dates were soon found to yield ages somewhat younger than expected, and there were many other technical problems associated with sample preparation and the operation of the counters.

Gas proportional counters soon replaced the solid-carbon method in all laboratories, with the samples being converted to gases such as carbon dioxide, carbon disulfide, methane, or acetylene.

Leave a Reply